See what is happening below the surface

Go beyond “Map contamination”.Measure biodegradation.Make better remediation decisions.

We add real-time measurement of oxygen, carbon dioxide and methane to membrane-interface-probe investigations. These additional measurements reveal the location, type and level of active biodegradation occurring underground.

  • ContaminationWhere is it?
  • Gas activityWhat’s happening?
  • BiodegradationIs nature working?
  • Better decisionsAct with confidence.

What the measurements give you

  • Find Active Zones

    Locate where biodegradation is occurring.

  • Understand Processes

    Identify aerobic or anaerobic conditions.

  • Improve Site Models

    Add a dynamic biological layer to your data.

  • Better Decisions

    Evaluate Natural Source Zone Depletion (NSZD) vs active remediation.

The Challenge

Delineation of the contamination in the subsurface tells only part of the story

Traditional investigations identify where contaminants are present. But vapor concentration alone doesn’t reveal if chemicals are degrading.

Because vapors migrate through soils of varying porosity and moisture, a detectable concentration may indicate presence without showing the source, preferential migration pathways or whether an active biodegradation process is occurring nearby.

Traditional Measurement

How much is here?

Measures vapor concentrations — is contaminant around here?

EcoRemediation Approach

How much biodegradation processes are active in the surrounding soil?

Measures gas concentrations and mass flux — how rapidly the surrounding formation is supplying these gases.

Patent Pending

The Technology

Adding the subsurface’s vital signs

Our technology enhances membrane-interface-probe (MIP) investigations by measuring three key gases in real time.

Oxygen, carbon dioxide and methane provide vital information about subsurface conditions and biodegradation activity.

Learn More About What We Measure

What we measure

  • O₂ — Oxygen

    Oxygen profiles contribute information about aerobic subsurface conditions and activity.

  • CO₂ — Carbon dioxide

    CO₂ concentration and flux patterns can help locate zones where aerobic biodegradation may be taking place.

  • CH₄ — Methane

    Methane concentration and mass flux can indicate zones associated with anaerobic biodegradation.

How It Works

From probe to insight in four simple steps

  1. Probe the subsurface

    A MIP probe is advanced through the soil to investigate different depths.

  2. Gases cross the membrane

    Compounds from the formation pass through the probe’s micro-porous membrane. Clean nitrogen sweeps the inside and carries them to the surface.

  3. Gases are measured

    Diagram: a field screen plotting three gas response curves against depth as the probe advances.

    Oxygen, carbon dioxide and methane are measured in real time along with contaminant vapors.

  4. Activity is calculated

    When the probe is stationary, we obtain gas concentrations and mass flux — how rapidly the surrounding formation is supplying the gas.

What You Gain

  • Find active biodegradation zones

    Locate where natural processes are occurring.

  • Identify process type and intensity

    Distinguish aerobic vs anaerobic activity and its strength.

  • Improve conceptual site models

    Add a dynamic biological layer to physical and chemical data.

  • Compare remediation options

    Evaluate Natural Source Zone Depletion (NSZD) with accurate data vs active remediation.

  • Save time and cost

    Gain more insight from the same investigation with minimal additional cost.

Applications

Better information for better environmental decisions

  • Preliminary Site Investigations
  • Industrial & Brownfield Properties
  • Petroleum-Contaminated Sites
  • Chlorinated-Solvent Sites
  • Natural Attenuation / NSZD Evaluations
  • Conceptual Site Model Updates
  • Remediation Strategy Selection
  • DNA sampling

Results & Validation

Validated from permeation experiments to field demonstration

A concentration reading tells us that a compound has been detected. A mass-flux measurement provides a different kind of information: is the surrounding formation continually supplying that gas?

Laboratory permeation study

The permeation study of May 2025 tested oxygen, carbon dioxide and methane across the full 0–20.8 % range. Permeation rates for the three gases are similar, and the mass transfer through the membrane appears quite steady.

The membrane is sintered PTFE powder in a stainless-steel mesh. Transport through it follows a pore-flow model driven by a pressure gradient, so the flux through the membrane is proportional to the gas-phase pressure outside it.

Sweep gasSweep gas + permeateTesting gasPermeate sideFeed sideMembraneO-ring seal
Laboratory permeation cell. Testing gas enters the feed side; clean sweep gas carries the permeated fraction from the permeate side to the detector.
0.000.200.400.600.8005101520Concentration in testing gas (%)Permeate (%)
  • O₂
  • CO₂
  • CH₄
Permeate concentration measured against the concentration of each gas in the testing gas.

Estimate of gas concentrations beside the MIP

Typical readings with a MIP for gas

Chart of gas concentration against time, from sixty seconds before the probe stops to sixty seconds after. Carbon dioxide rises from about four percent to a peak of ten percent shortly after the probe stops, then falls back to about two percent. Methane and oxygen stay flat. One bracket marks the sample trip time before the peak, another the residence time while the probe is stationary.
As the probe advances, the reading tracks what the trunkline delivers. When the probe stops, gas concentration in the formation may be assessed once the sample arrives to the detectors at surface and afterwards, the reading will equilibrate to the level the formation can sustain.

With the MIP, gas mass flux are estimated

Two panels side by side. On the left, headed low mass flux of gas, a few thin arrows reach a cube of formation against the probe membrane. On the right, headed high mass flux of gas, many heavy arrows converge on it.
  • When mass flux is lower than permeation rate, readings will decrease within a minute.
  • When mass flux is higher than permeation rate, readings stay steady.
The same membrane, two states. What separates them is whether the formation can keep supplying gas as fast as the membrane takes it away.

An innovative approach to optimize information from one mobilisation

(Examples of readings obtained during a field demonstration: Location B)

Cutaway illustration of a contaminated site. A truck-mounted direct-push rig stands on the surface and advances a probe through the vadose zone, past the water table at thirty feet, to forty-two feet. Two magnified insets show bacterial growth in the soil beside the probe at that depth.
One push, and we determine the depth at which the gas reading say biodegradation is under way beside the probe.

40 feet BGS

Chart of gas concentration against time at forty feet. Methane steps up from about two and a half percent to a plateau near nine percent while the probe is stationary, then eases back to five. Carbon dioxide barely lifts off zero to about two percent. Oxygen stays flat at zero.

Some CO₂ and CH₄ concentrations.

But no CO₂ mass flux, and low CH₄ mass flux.

Potential of some anaerobic biodegradation nearby.

42 feet BGS

Chart of gas concentration against time at forty-two feet, two feet deeper. Methane climbs steeply from about five percent to roughly thirty percent and holds there. Carbon dioxide stays near two percent and oxygen at zero.

Some CO₂ and no mass flux.

But high CH₄ concentrations and mass flux.

High anaerobic biodegradation beside membrane.

Add a dynamic biological layer to your data

A three-dimensional conceptual site model on a black background: stacked geological layers beneath building footprints, vertical borehole traces, and a contoured vapour plume in blue, green and red modelled below the block.
Traditional HRSC provides CSM based on vapors analysis alone.
The same three-dimensional block, with modelled carbon dioxide shown as a mottled red body through the lower strata and spreading beneath it.
Carbon dioxide concentrations0 %20 %
  • Gas concentration and mass flux measurement “in-real time” reveal active biodegradation zones.
  • This enhancement requires minimal additional cost.
  • Addresses subsurface heterogeneity.
  • When performing DNA sampling, avoid “Low-Abundance Organisms Samples”.

Integrate gas analysis during preliminary HRSC.

Innovation

Presence is not the same as activity

A gas can be present without an active process nearby.

Vapours are not gases

Since the mid-1990s, membrane-interface probes have been used to locate contamination by analysing vapours. The equipment has focused on vapours alone since its inception.

The behaviour of the two is markedly distinct, particularly in how they migrate through soils of varying porosity. Adding gas detectors to an instrument built for vapours is what makes biodegradation visible.

Vapour

A substance that exists in a liquid state at standard temperature and pressure.

Benzene, trichloroethylene, water

Gas

A substance that exists in a gaseous state at standard temperature and pressure.

Oxygen, methane, carbon dioxide

What was added

Three detectors were integrated so the gases in the instrument’s effluent could be analysed alongside the contaminant vapours.

  • 01One electrochemical detector for oxygen
  • 02One infrared detector for methane
  • 03One infrared detector for carbon dioxide

Together they give real-time, semi-quantitative assessments of gas concentrations in the formation beside the probe.

How much is here?
Concentration tells you how much gas is present.
How much biodegradation processes are active in the surrounding soil?
Mass flux tells you how rapidly the surrounding formation is supplying that gas.
  • Go beyond concentration

    Determine whether gases are simply present or actively being supplied by the surrounding formation.

  • Locate active zones

    Identify where biodegradation appears to be occurring, not simply where contamination has been detected.

  • Improve the Conceptual Site Model

    Add a dynamic biological layer to the contaminant distribution.

  • Minimal incremental cost

    The innovation can be incorporated into a preliminary investigation without significant additional cost.

About EcoRemediation

More information from the same investigation and the same mobilization

EcoRemediation Inc. is an environmental consulting business based in Montreal, Quebec, led by Andre Tartre.

The practice adds real-time measurement of oxygen, carbon dioxide and methane to membrane-interface-probe investigations. These additional measurements reveal the location, type and level of active biodegradation occurring underground.

The approach is designed to add information to a conventional preliminary site investigation rather than to create an entirely separate investigation program — during a preliminary investigation across the whole site, or during an update of the Conceptual Site Model, on the same mobilization.

Conventional site investigation shows where contamination is. This technology adds information about what is actually happening there, whether natural biodegradation is active, where it is active, and how strongly it is occurring.

Portrait of Andre Tartre, founder of EcoRemediation Inc., in a dark pinstriped suit and blue tie against a plain light background.

Andre Tartre

Founder, EcoRemediation Inc.

atartre@eco-remediation.ca

Understand What Is Happening Beneath Your Site

Add real-time gas and biodegradation assessment to your next site-characterization program.

Contact Us

Talk to us about your site

Have a contaminated site under investigation? Write to us about adding real-time gas and biodegradation assessment to your next site-characterization program.

Write to

atartre@eco-remediation.ca

Useful things to include

  • What stage the investigation has reached;
  • Contaminants of concern, if known, volume;
  • If an active remediation plan has already been applied to the site.